Organic-solvent/water/ionic-liquid triphasic system for the fractional extraction of divalent metal cations.

نویسندگان

  • Takeshi Takata
  • Naoki Hirayama
چکیده

A novel cyclohexane/water/ionic-liquid (1-butyl-3-methylimidazolium hexafluorophosphate, [bmim][PF6]) triphasic extraction system was studied for a possible fractional extraction of divalent metal cations with co-using 8-quinolinol (HQ) and tri-n-octylphosphine oxide (TOPO) as competitive extractants. In this system, Ni2+ was extracted into the [bmim][PF6] phase as a Q(-)-complex, whereas each of Mn2+, Zn2+, Cd2+ and Pb2+ was extracted into the cyclohexane phase as an ion-pair of a cationic TOPO-complex and PF6-. A suitable selection of extractants and ionic liquid can result in developing a powerful triphasic fractional extraction system.

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عنوان ژورنال:
  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry

دوره 25 11  شماره 

صفحات  -

تاریخ انتشار 2009